Key Takeaways
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Tooling Must Withstand Extreme Heat – High-temperature resins require molds capable of handling temperatures up to 400°F (205°C) or more, with careful attention to tooling material, heating systems, cooling systems, and venting to prevent defects and maintain part quality.
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Resin Selection Depends on Application Needs – Materials like PEEK, Torlon, PPS, and Ultem offer varying balances of heat tolerance, chemical resistance, processability, and cost, making it essential to match resin properties to the part’s performance requirements.
- Processing Demands Are Higher for High-Temp Resins – These resins are hygroscopic, abrasive, and require specialized drying, purging, and high-temperature-capable equipment, which can increase wear on tooling and machinery.
When working with high-temperature plastic injection molding, both the tooling and resin selection are critical due to the extreme temperatures involved. High-temperature resins can be a less expensive option for metal-to-plastic conversions in high-heat applications. The following overview outlines key considerations and compares popular high-performance resins:
Tooling Considerations
- Tooling Material
High-temp resins require tooling that can withstand mold temperatures up to 400°F (205°C) or more:
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- H13 Tool Steel: Common choice due to high strength and thermal fatigue resistance.
- Stainless Steel (e.g., 420 SS): Useful when corrosion resistance is needed.
- Beryllium-Copper Inserts: For improved thermal conductivity in specific mold areas.
- Heater Systems
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- Use oil or electric cartridge heaters to maintain high mold temps (350°F–400°F / 177°C–205°C).
- Thermal insulation is critical to reduce energy loss and protect operators.
- Cooling System
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- Cooling must be controlled and uniform.
- High-temp molds may need pressurized water or oil systems.
- Ventilation
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- High-temp resins outgas more—proper venting prevents short shots and burning.
- Surface Finish & Mold Design
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- Polished cavities reduce resin sticking.
- Mold must account for high shrinkage or warping behavior.
- Highly recommend MoldFlow analysis and DFM review before launching tooling.
Resin Comparison (Temp Ratings & Notes)
Resin | Max Use Temp (°F / °C) | Processing Temp (°F / °C) | Mold Temp (°F / °C) | Notes |
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PEEK (Polyether ether ketone) | ~480°F / 250°C | 680–750°F / 360–400°C | 350–400°F / 175–205°C | Excellent strength, chemical and creep resistance. Expensive and demanding to mold. |
Torlon (PAI – Polyamide-imide) | ~500°F / 260°C | 650–700°F / 343–371°C | 350–400°F / 175–205°C | Superior strength and dimensional stability. Hygroscopic; needs thorough drying. |
Polyamide (Nylon 6/6) | ~300°F / 150°C | 500–550°F / 260–290°C | 150–200°F / 65–93°C | Easy to process; absorbs moisture and may warp. Not ideal for ultra-high-temp applications. |
Polyphenylene sulfide (PPS) | ~425°F / 220°C | 600–650°F / 315–343°C | 275–325°F / 135–160°C | Great chemical resistance and dimensional stability. Flows well; good for thin walls. |
Polyetherimide (Ultem) | ~340°F / 170°C | 650–750°F / 343–400°C | 275–350°F / 135–175°C | Transparent amber, high heat and flame resistance. Can be brittle if not processed properly. |
Additional Considerations
- Material Handling
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- All these resins are hygroscopic—must be dried before molding (some require 4–16 hours at 250–300°F / 120–150°C).
- Clean purging procedures are critical to prevent degradation or contamination.
- Machine Capabilities
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- High-temp barrel heaters and specialized screws required.
- Need machines rated for injection temps up to 800°F (430°C) for PEEK or Torlon.
- Wear and Tear
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- These materials are abrasive and can erode tooling/screws.
- Use nitrided or coated screws and barrels.
Would you like a downloadable comparison chart or need help selecting the best resin for a specific application (e.g., aerospace, automotive, medical)? Contact us at info@vitalplastics.com or call us at 715-688-4820.
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